*Figure 11. Fourier convolution is used here to
determine how the optical spectrum in Window 1 (top left) will
appear when scanned with a spectrometer whose slit function
(spectral resolution) is described by the Gaussian function in
Window 2 (top right). The Gaussian function has already been
rotated so that its maximum falls at x=0. The resulting
convoluted optical spectrum (bottom center) shows that the two
lines near x=110 and 120 will not be resolved but the line at
x=40 will be partly resolved. Fourier convolution is used in
this way to correct the analytical curve non-linearity caused by
spectrometer resolution, in the “Tfit”
method for absorption spectroscopy. *

In
practice, the calculation is usually performed by point-by-point
multiplication of the two signals in the Fourier domain. First,
the Fourier transform of each signal is obtained. Then the two
Fourier transforms are multiplied point-by-point by the rules for
complex multiplication and the result is then inverse Fourier
transformed. Fourier transforms are usually expressed in terms of
"complex
numbers", with real and imaginary parts; if the Fourier
transform of the first signal is a + ib,
and the Fourier transform of the second signal is c + id, then the product of the two Fourier
transforms is (a + ib)(c + id)
= (ac - bd) + i(bc +
ad). Although this seems
to be a round-about method, it turns out to be faster then
the shift-and-multiply algorithm when the number of points in the
signal is large. Convolution can be used as a powerful and general
algorithm for smoothing and differentiation. Many computer
languages will perform this operation automatically when the two
quantities divided are complex.

Fourier convolution can also be used as a very general algorithm
for the smoothing and differentiation of digital signals, by
convoluting the signal with a (usually) small set of numbers
representing the convolution vector. Smoothing is performed by
convolution with sets of positive numbers, e.g. [1 1 1] for a
3-point boxcar. Convolution with [–1 1] computes a first
derivative; [1 -2 1] computes a second derivative. Successive
convolutions by Conv1 and then Conv2 is equivalent to one
convolution with the convolution of Conv1 and Conv2. First
differentiation with smoothing is done by using a convolution
vector in which the first half of the coefficients are negative
and the second half are positive (e.g.[-1 -2 0 2 1]).

**Simple whole-number convolution vectors:**

**Smoothing**

`[1 1 1] = 3 point boxcar (sliding
average) smooth`

`[1 1 1 1] = 4 point boxcar
(sliding average) smooth`

`[1 2 1]
= 3 point triangular smooth`

`[1 2 3 2 1] = 5 point
triangular smooth
[1 4 6 4 1] = 5 point
Gaussian smooth
[1 4 8 10 8 4 1] = 7 point Gaussian
smooth
[1 4 9 14 17 14 9 4 1] = `

` `**Differentiation:**

`[-1 1]
First derivative`

`[1 -2 1]
Second derivative`

`[1 -2 1 -1] Third derivative`

`[1 -4 6 -4 1] Fourth derivative`

**Results of successive convolution by two vectors Conv1 and
Conv2:**

**Conv1
Conv2 **** ** **Result
Description**

`[1 1 1] [1 1 1] = [1 2 3
2 1] Triangular smooth`

`[1 2 1] [1 2 1] =
[1 4 6 4 1] Pseudo-Gaussian smooth`

`[-1 1] [-1
1] = [1 -2 1]
2nd derivative`

`[-1 1] [1 -2 1] =
[1 -3 3 -1] 3rd derivative`

`[-1 1] [1 1
1] = [1 0 0 -1) 1st derivative
gap-segment`

`[-1 1] [1 2
1] = [1 1 -1 -1) Smoothed 1st
derivative`

`[1 1 -1 -1] [1 2 1] = [1 3 2 -2 -3
-1] same with more smoothing`

`[1 -2 1] [1 2 1] = [1 0
-2 0 1] 2nd derivative gap-segment`

` rectangle rectangle = triangle or trapezoid
(depending on relative widths)
Gaussian Gaussian = Gaussian of greater
width
Gaussian Lorentzian = Something in between `

SPECTRUM, the freeware signal-processing application for Mac OS8 and earlier, includes convolution and auto-correlation (self-convolution) functions.

Spreadsheets can be used to perform "shift-and-multiply" convolution for small data sets (for example, MultipleConvolution.xls or MultipleConvolution.xlsx for Excel and MultipleConvolutionOO.ods for Calc), but for larger data sets the performance is much slower that Fourier convolution (which is much easier done in Matlab or Octave than in spreadsheets).

Matlab and Octave have a built-in function for convolution of two vectors:

smooths the vector y with a 5-point unweighted sliding average (boxcar) smooth, and

smooths the vector y with a 5-point triangular smooth. The optional argument 'same' returns the central part of the convolution that is the same size as y.

Differentiation is carried out with smoothing by using a convolution vector in which the first half of the coefficients are negative and the second half are positive (e.g.[-1 0 1],[-2 -1 0 1 2], or [-3 -2 -1 0 1 2 3]) to compute a first derivative with increasing amounts of smoothing. The

ans =

1 0 -2 0 1

The next example creates an exponential trailing transfer function (c), which has an effect similar to a simple RC low-pass filter, and applies it to y.

In each of the above three examples, the result of the convolution is divided by the sum of the convolution transfer function, in order to insure that the convolution has a net gain of 1.000 and thus does not effect the area under the curve of the signal. Alternatively, you could perform the convolution yourself

iSignal version 5.7 has a

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