Variable sheet:
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St Input Name Output Unit Comment
5 cg µg/mL concentration (g/L,g/mL,mg/mL,µg/mL,pp
5 F mL/min solution flow rate (mL/sec, mL/min)
.03 epsilon overall atomization efficiency
10 Q L/min total gas flow rate (L/sec, L/min)
2000 T K Temperature in K
1 nT moles relative # moles burnt gases
1 n298 moles relative # moles unburnt gases
63.5 MW formula weight of analyte (g/mole)
324.7 lambda nm wavelength of light (nm, A, µm, cm)
1E8 Aji sec-1 Einstein A coefficient (sec-1)
2 go statistical weight of lower state
4 g1 statistical weight of upper state
1 l cm path length (cm, mm, µm)
Rlambda 26.185157 mA/watt radiant cathode sensitivity (amps/watt
.1 Klambda Quantum efficiency of photocathode
500000 m photomultiplier gain
50 W µm slit width (cm, mm, µm)
5 H mm slit height (cm, mm, µm)
.02 omega sr solid angle of monochromator (steradia
.6 Top transmission factor of monochromator
c .00007874 mole/L analyte molar concentration (mole/L)
freq 9.2331E14 Hz frequency (Hz)
E 6.118E-19 J energy (Joule, erg, eV, kcal/mole)
v 30797.659 cm-1 wavenumber (cm-1)
ef 6.7114094 gas expansion factor
n1 50.272252 cm-3 Number in upper state (cm-3)
no 1.0559E11 cm-3 Number in lower state (cm-3)
Be 2.448E-10 w/sr/cm2 total line emission radiance (watts/st
Ie 9.613E-11 amps photoanodic current (amps)
PhotFlu 12001.616 sec-1 photon flux on detector, photons/sec
Rcp 1200.1616 sec-1 photoelectron emission rate, sec-1
PhotSNR 34.643349 Signal-to-photon-noise ratio
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Rule sheet.
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E = (6.6261E-34)*freq
freq = (2.998E10)/lambda
lambda = 1/v
no=6e17*F*epsilon*c/(Q*ef) " Equation 7-9
ef=(nT*T)/(n298*298) " Equation 7-8
cg=MW*c
n1 = no*(g1/go)*exp(-E/(T*1.3805e-23)) " Boltzman equation 2-14
Be=Aji*E*n1*l/(4*Pi()) " Equation 2-15
Ie=m*Rlambda*W*H*omega*Top*Be
PhotFlux=Aji*n1*W*H*omega*Top/(4*Pi())
Rcp=Klambda*PhotFlux
PhotSNR=Rcp/sqrt(Rcp)
Rlambda=(Klambda*1.602e-19)/E " Paragraph after equation 4-28
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