Counter-Current Liquid-Liquid Extraction

Computer Methods in Chemical Engineering


Problem Statement: The following is a schematic diagram of an N-stage counter-current extraction operation, where E is the extract stream, R is the raffinate stream.

       y1 +-----+  y2          yi  +-----+ yi+1         yN  +-----+  yN+1
   E <----|     |<----- ... <-----|     |<----- ... <-----|     |<----- E
          |stage|                 |stage|                 |stage|
          |  1  |                 |  i  |                 |  N  |
   R ---->|     |-----> ... ----->|     |-----> ... ----->|     |-----> R
      x0  +-----+  x1         xi-1 +-----+  xi         xN-1 +-----+  xN


The following equations describe this counter-current extraction process.
    xi-1 - (1+S)*xi + S*xi+1 = 0    for i=1..N

    yi=K*xi

    where x = the composition of the raffinate phase, R
          y = the composition of the extract phase, E
          K = the partition coefficient
          S = K*E/R
          N = the number of stages
Another equivalent form of the first equation is:
     x0-xN     SN+1-S
    ------ = -------
    x0-xN+1    SN+1-1
Given E=200 lb/hr, R=300 lb/hr, K=3, and inlet raffinate and extract compositions of x0=0.03 and yN+1=0, respectively, write a program to determine the number of stages, N, required for the process to achieve an exit raffinate composition of xN=0.001. (Note that N is an integer -- you either have a stage or you don't.) Furthermore, output the composition of the raffinate phase at each stage.

Solution:


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Computer Methods in Chemical Engineering -- Counter-Current Liquid-Liquid Extraction
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