Material Safety Data
Sheet
Sodium dodecyl sulfate
ACC# 08485
Section 1 - Chemical Product and Company
Identification |
MSDS Name: Sodium dodecyl sulfate
Catalog Numbers: AC226141000, AC226145000, AC230421000,
AC230425000, AC419530010, AC419530250, AC419531000, S799941, S799942, BP166-100,
BP166-5, BP166-500, NC9973507, O2674-25, S529-3, S529-500
Synonyms:
SDS; Sodium lauryl sulfate; Dodecyl sodium sulfate; Sulfuric acid monododecyl
ester, sodium salt; SLS; Dodecyl hydrogen sulfate sodium salt.
Company
Identification:
Fisher
Scientific
1 Reagent
Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For
International CHEMTREC assistance, call: 703-527-3887
Section 2 -
Composition, Information on Ingredients |
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
151-21-3 |
Sodium lauryl sulfate |
>85 |
205-788-1 |
Hazard
Symbols: XI
Risk Phrases: 36/38
Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white solid. Causes eye and skin irritation.
Warning! May cause respiratory tract irritation.
Target
Organs: Eyes, skin.
Potential Health
Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. Contact with the skin defats
the skin. Sodium lauryl sulfate can produce allergic sensitivity reactions. May
produce drying effect on skin. Sodium lauryl sulfate increases the per meability
of the skin.
Ingestion: Causes gastrointestinal irritation
with nausea, vomiting and diarrhea.
Inhalation: Causes
respiratory tract irritation. May cause severe allergic respiratory reaction.
May cause severe irritation of the respiratory tract with sore throat, coughing,
shortness of breath and delayed lung edema.
Chronic:
Repeated exposure may cause allergic respiratory reaction (asthma). Chronic
inhalation may lead to decreased pulmonary function.
Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid.
Skin: Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid if irritation develops or persists.
Ingestion: Do NOT induce vomiting. If victim is conscious
and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation: Get
medical aid immediately. Remove from exposure and move to fresh air immediately.
If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.
Notes to Physician: Treat symptomatically and
supportively.
Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Dusts at sufficient concentrations can form explosive mixtures with air.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion.
Extinguishing Media: Use
extinguishing media most appropriate for the surrounding fire.
Flash
Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not
available.
NFPA Rating: (estimated) Health: 2;
Flammability: 1; Instability: 0
Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Reduce airborne dust and prevent
scattering by moistening with water. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Wash hands
before eating. Remove contaminated clothing and wash before reuse. Avoid contact
with eyes, skin, and clothing. Use only with adequate ventilation. Avoid
breathing dust.
Storage: Store in a cool, dry place. Store
in a tightly closed container.
Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
Sodium lauryl sulfate |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Sodium
lauryl sulfate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate protective gloves to
prevent skin exposure.
Clothing: Wear appropriate
protective clothing to prevent skin exposure.
Respirators: Follow the
OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.
Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: Faint odor of fatty
substances.
pH: Not available.
Vapor Pressure: Negligible
Vapor Density: Not available.
Evaporation Rate:Not
available.
Viscosity: Not available.
Boiling Point:
decomposes
Freezing/Melting Point:204 - 207 deg C
Decomposition Temperature:Not available.
Solubility: +/-
150 G/L (20°C)
Specific Gravity/Density:Not available.
Molecular Formula:C12H25NaO4S
Molecular Weight:288.38
Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: Dust generation, excess heat.
Incompatibilities with Other
Materials: Strong oxidizing agents.
Hazardous Decomposition
Products: Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 -
Toxicological Information |
RTECS#:
CAS# 151-21-3: WT1050000
LD50/LC50:
CAS#
151-21-3:
Draize test, rabbit, eye: 100 mg/24H Moderate;
Draize test,
rabbit, eye: 250 ug Mild;
Draize test, rabbit, eye: 2 mg;
Draize test,
rabbit, eye: 10 mg Moderate;
Draize test, rabbit, skin: 50 mg/24H
Severe;
Draize test, rabbit, skin: 25 mg/24H Moderate;
Draize test,
rabbit, skin: 250 mg/24H Moderate;
Draize test, rabbit, skin: 10
mg/24H;
Draize test, rabbit, skin: 50 mg/24H Mild;
Inhalation, rat: LC50 =
>3900 mg/m3/1H;
Oral, rat: LD50 = 1288 mg/kg;
Carcinogenicity:
CAS# 151-21-3: Not listed by ACGIH, IARC, NIOSH,
NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects:
No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data
available.
Section 12 -
Ecological Information |
No information available.
Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
Shipping Name: |
No information available. |
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No information available. |
Hazard Class: |
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UN Number: |
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Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 151-21-3 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
CERCLA
Hazardous Substances and corresponding RQs
None of the chemicals in this
material have an RQ.
SARA Section 302 Extremely Hazardous
Substances
None of the chemicals in this product have a TPQ.
SARA
Codes
CAS # 151-21-3: acute.
Section 313
No chemicals are
reportable under Section 313.
Clean Air Act:
This material does
not contain any hazardous air pollutants. This material does not contain any
Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA. None of the chemicals in this
product are listed as Priority Pollutants under the CWA. None of the chemicals
in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly
hazardous by OSHA.
STATE
CAS# 151-21-3 is not present on state
lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European
Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse
immediately
with plenty of water and seek medical advice.
S 37/39 Wear
suitable gloves and eye/face
protection.
WGK (Water
Danger/Protection)
CAS# 151-21-3: 2
Canada - DSL/NDSL
CAS#
151-21-3 is listed on Canada's DSL List.
Canada - WHMIS
This
product has a WHMIS classification of D2B.
Canadian Ingredient Disclosure
List
CAS# 151-21-3 is listed on the Canadian Ingredient Disclosure
List.
Exposure Limits
Section 16 -
Additional Information |
MSDS Creation Date:
2/04/1998
Revision #4 Date: 5/09/2003
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.